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ZnAl2O4@SiO2 nanocomposite catalyst for the acetylation of alcohols, phenols and amines with acetic anhydride under solvent-free conditions
Spinel-type oxide Zinc aluminate Silica Sol-gel process Nanocomposite Heterogeneous catalyst Acetylation Solvent-free condition
2014/3/8
A ZnAl2O4@SiO2 nanocomposite was prepared from metal nitrates and tetraethyl orthosilicate by the sol-gel process, and characterized by X-ray diffraction, Fourier transform infrared, transmission elec...
Boehmite nanoparticle catalyst for the one-pot multicomponent synthesis of 3,4-dihydropyrimidin-2-(1H)-ones and thiones under solvent-free conditions
Boehmite nanoparticle One-pot synthesis Multicomponent synthesis Dihydropyrimidine Solvent-free
2014/3/8
A simple, green, and efficient synthesis protocol for the synthesis of 3,4-dihydropyrimidin-2-(1H)-ones using boehmite nanoparticles as catalyst was developed. It did not use any toxic metal catalysts...
Poly(4-vinylpyridinium) perchlorate as an efficient solid acid catalyst for the chemoselective preparation of 1,1-diacetates from aldehydes under solvent-free conditions
Poly(4-vinylpyridinium) perchlorate Chemoselective Supported catalyst Acylation Aldehyde
2014/3/8
Poly(4-vinylpyridinium) perchlorate has been used as a supported, recyclable, environmentally-benign catalyst for the formation of acylals from aliphatic and aromatic aldehydes in good to excellent yi...
Poly(4-vinylpyridinium)hydrogen sulfate: A novel and efficient catalyst for the synthesis of 13-aryl-indeno[1, 2-b]naphtha[1, 2-e]pyran-12(13H)-ones under solvent-free conditions
Poly(4-vinylpyridinium)hydrogen sulfate Indenonaphthopyrans, H-indene-1,3-dione β-Naphthol
2014/3/11
An facile and efficient protocol for the synthesis of 13-aryl-indeno[1,2-b]naphtha[1,2-e]pyran- 12(13H)- ones has been developed that proceeds via the one-pot three-component sequential reaction of an...
Aldol condensations of a variety of different aldehydes and ketones under ultrasonic irradiation using poly(N-vinylimidazole) as a new heterogeneous base catalyst under solvent-free conditions in a liquid-solid system Nader Ghaffari Khaligha, Taraneh Mihankhahb（图）
Ultrasound-assisted reaction Liquid-solid system Poly(N-vinylimidazole) Aldol condensation, Solvent-free
2013/12/5
An ultrasound-assisted aldol condensation reaction has been developed for a range of ketones with a variety of aromatic aldehydes using poly(N-vinylimidazole) as a solid base catalyst in a liquid-soli...
Fe3O4 Nanoparticles as an Efficient and Magnetically Recoverable Catalyst for the Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones under Solvent-Free Conditions（图）
dihydropyrimidinones dihydropyrimidinthiones ferroferric oxide nanoparticle one-pot condensation solvent-free
2013/10/12
The catalytic activity of Fe3O4 nanoparticles (NPs) in a one-pot three component condensation reaction consisting of an aromatic aldehyde, urea or thiourea, and a β-dicarbonyl under solvent-free condi...
Tetrabutylammonium hexatungstate [TBA]2[W6O19]: Novel and reusable heterogeneous catalyst for rapid solvent-free synthesis of polyhydroquinolines via unsymmetrical Hantzsch reaction（图）
Heterogeneous catalysis Polyhydroquinolines Tetrabutylammonium hexatungstate
2013/9/26
A novel, efficient, and environmentally friendly method for the synthesis of polyhydroquinoline derivatives by a one-pot, four-component unsymmetrical Hantzsch condensation of dimedone, aldehydes, eth...
Ionic-liquid-catalyzed green synthesis of coumarin derivatives under solvent-free conditions（图）
Ionic liquid Pechmann reaction Solvent-free synthesis Phloroglucinol Pyrano[2,3-h]coumarin
2013/9/25
Brönsted acidic ionic liquids, namely 2-pyrrolidonium hydrogen sulfate, N-methyl-2-pyrrolidonium hydrogen sulfate, N-methyl-2-pyrrolidonium dihydrogen phosphate, (4-sulfobutyl)tris(4-sulfophenyl)...
Solvent-Free Selective Cross-Aldol Condensation of Ketones with Aromatic Aldehydes Efficiently Catalyzed by a Reusable Supported Acidic Ionic Liquid（图）
cross-aldol condensation solvent-free condition supported acidic ionic liquid ketone aromatic aldehyde
2013/10/4
A newly prepared catalyst consisting of acidic ionic liquid 1-(4-sulfonic acid)butylpyridinium hydrogen sulfate supported on silica was used to catalyze the cross-aldol condensation of ketones with ar...
A Rapid and Green Method for Solvent-Free Synthesis of 1,8-Dioxodecahydroacridines Using Tetrabutylammonium Hexatungstate as a Reusable Heterogeneous Catalyst（图）
1,8-dioxodecahydroacridine solvent-free condition tetrabutylammonium hexatungstate
2013/10/4
Tetrabutylammonium hexatungstate, [TBA]2[W6O19], has been used as an efficient, inexpensive, and recyclable green catalyst for the one-pot three-component synthesis of 1,8-dioxodecahydroacridines by t...
Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol（图）
hexacyanoferrate nanoparticle heterogeneous catalyst benzyl alcohol benzaldehyde
2013/10/9
Nickel hexacyanoferrate nanoparticles were synthesized and characterized using elemental analysis, thermal analysis, infrared spectroscopy, and X-ray diffraction. A FE-SEM image of the nickel hexacyan...
Cobalt Nanoparticles Promoted Highly Efficient One Pot Four-Component Synthesis of 1,4-Dihydropyridines under Solvent-Free Conditions（图）
cobalt nanoparticle 1,4-dihydropyridine four-component condensation heterogeneou catalyst magnetically separable catalyst
2013/10/10
A straightforward and general method has been developed for the synthesis of C5-unsubstitiuted 1,4-dihydropyridines by a reaction using dimedone, acetophenone, aromatic aldehydes, and ammonium acetate...
Silica Sulfuric Acid: An Efficient Heterogeneous Catalyst for the One-Pot Synthesis of 1,4-Dihydropyridines under Mild and Solvent-Free Conditions（图）
aldehyde ethyl acetoacetate ammonium acetate silica sulfuric acid 1,4-dihydropyridine
2013/10/12
A series of 1,4-dihydropyridines have been prepared by a one-pot condensation of aldehydes, ethyl acetoacetate, and ammonium acetate in the presence of a heterogeneous catalyst silica sulfuric acid at...
Formylation of Alcohol with Formic Acid under Solvent-Free and Neutral Conditions Catalyzed by Free I2 or I2 Generated in Situ from Fe(NO3)3•9H2O/NaI（图）
alcohol formic acid formylation iodine in situ iodine solvent-free
2013/10/15
Different alcohols were formylated by formic acid under solvent-free conditions in the presence of iodine as the catalyst with good-to-high yields at room temperature. I2 generated in situ from Fe(NO3...
Lipase Mediated Isoamyl Acetate Synthesis in Solvent-Free System Using Vinyl Acetate as Acyl Donor
isoamyl acetate immobilized lipase Rhizopus oryzae NRRL 3562
2009/6/24
Synthesis of isoamyl acetate, a flavour ester extensively used in food industry, has been carried out in a solvent-free system. In the present study, an attempt has been made to enhance the isoamyl ac...