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Chemistry of Bicyclic Endoperoxides Derived from Dihydropyridine Derivatives: Attempted Synthesis of Polyhydroxypiperidine Derivatives
Azasugar derivatives amino sugars singlet oxygen bicyclic endoperoxides
2010/4/19
To achieve the synthesis of azasugar derivatives with the utilization of singlet oxygen, pyridine was used as the starting material. The reduction of pyridine followed by a singlet oxygen reaction aff...
Studies on the Mechanism of Base-Catalyzed Decomposition of Bicyclic Endoperoxides
Bicyclic endoperoxides Kornblum-Delamare reaction base-catalyzed decomposition kinetic study
2010/4/21
Kinetic studies were performed to clarify the Kornblum-Delamare reaction mechanism of bicyclic endoperoxides. Ascaridol and 1,4-diphenyl-2,3-dioxa-bicyclo[2.2.2]oct-5-ene, not having a -protons, did n...