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Quantitative,Directional Measurement of Electric Field Heterogeneity Within an Enzyme Active Site
Quantitative Directional Measurement Electric Field Heterogeneity Enzyme Active Site
2016/5/25
Extensive structural studies of enzymes have revealed that biological catalysis occurs within sequestered active site crevices, where reacting substrates are surrounded by an anisotropic and chemicall...
Controlling Two-Dimensional Tethered Vesicle Motion Using an Electric Field:Interplay of Electrophoresis and Electro-Osmosis
Electric field effects Electrophoresis Electroosmosis DNA Lipids Dynamic response
2016/5/24
We recently introduced methods to tether phospholipid vesicles or proteoliposomes onto a fluid-supported lipid bilayer using DNA hybridization (Yoshina-Ishii, C.; Miller, G. P.; Kraft, M. L.; Kool, E....
Lateral Reorganization of Fluid Lipid Membranes in Response to the Electric Field Produced by a Buried Charge
Thuja dolabrata var. hondai cell culture beta-thujaplicin hinokitiol semi-continuous culture system
2016/5/23
A thermodynamic model describing multicomponent fluid membranes under the influence of lateral forces due to a buried charge is developed to estimate the magnitude and dynamics of field-induced latera...
Electric Field Effects in Multicomponent Fluid Lipid Membranes
melatonin impurities bulk drug substance analytical methods impurity profile residual solvent stability purity
2016/5/23
A thermodynamic model of multicomponent fluid membranes under the influence of lateral forces is described. Membrane components are characterized by their effective molecular areas, molecular charges,...
Electric Field-Induced Critical Demixing in Lipid Bilayer Membranes
Cardiolipins Electric Stimulation Electricity Fluorescent Dyes Lipid Bilayers Membranes, Artificial Microscopy, Fluorescence Models, Chemical Models, Molecular hosphatidylcholines Phosphatidylethanolamines Thermodynamics
2016/5/23
Electric fields can induce lateral reorganization of lipids in fluid bilayer membranes. The resulting concentration profiles readily are observed in planar-supported bilayers by epifluorescence micros...
Electric Field-Induced Reorganization of Two-Component Supported Bilayer Membranes
Electric Field-Induced Two-Component Bilayer Membranes
2016/5/23
Application of electric fields tangent to the plane of a confined patch of fluid bilayer membrane can create lateral concentration gradients of the lipids. A thermodynamic model of this steady-state b...
Electric Field-Induced Concentration Gradients in Planar Supported Bilayers
Biophysical Phenomena Biophysics Diffusion Electricity Fluorescent Dyes Lipid Bilayers Microscopy,Fluorescence Models,Chemical
2016/5/23
A simple method of generating electric field-induced concentration gradients in planar supported bilayers has been developed. Gradients of charged, fluorescently labeled probes were visualized by epif...
Temperature Dependence of the Electric Field Modulation of Electron-Transfer Rates:Charge Recombination in Photosynthetic Reaction Centers
solar energy inorganic, organic, physical and analytical chemistry photosynthesis reaction kinetics electric fields electron transfer entropy experimental data free energy mathematical models
2016/5/23
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
Electric Field Effects on Kinetics of Electron Transfer Reactions:Connection Between Experiment and Theory
ADSORPTION KINETICS PROTEINS STRUCTURAL STABILITY
2016/5/23
The dependence of the rate constant for electron transfer on energy can be systematically studied by measuring kinetics in an applied electric field. General relationships are developed between observ...
Electric Field Effects on Emission Line Shapes when Electron Transfer Competes with Emission:an Example from Photosynthetic Reaction Centers
RHODOBACTER-SPHAEROIDES R-26 PRIMARY CHARGE SEPARATION RHODOPSEUDOMONAS-VIRIDIS BACTERIAL PHOTOSYNTHESIS FEMTOSECOND SPECTROSCOPY PROTEIN SUBUNITS 3A RESOLUTION PRIMARY DONOR SPECTRA
2016/5/23
Electron-transfer reactions are expected to be particularly sensitive to externally applied electric fields because of the presence of charge-separated, dipolar states, and the effects of the field on...
Electric Field Effects on the Initial Electron-Transfer Kinetics in Bacterial Photosynthetic Reaction Centers
solar energy inorganic, organic, physical and analytical chemistry photosynthetic reaction centers electron transfer calculation methods electric fields kinetics low temperature photochemistry chemistry 140500* -- solar energy conversion
2016/5/23
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net...
Electric Field Modulation of Electron Transfer Reaction Rates in Isotropic Systems:Long-Distance Charge Recombination in Photosynthetic Reaction Centers
CORROSION PRODUCT NICKEL FERRITE MAGNETITE PH SOLUBILITY PWR STEAM GENERATORS
2016/5/23
A general method is demonstrated for experimentally obtaining the rate constant of electron transfer as a function of the free energy of the reaction in nonoriented systems. An external electric field...
Structure-Based Analysis of the Initial Electron Transfer Step in Bacterial Photosynthesis: Electric Field Induced Fluorescence Anisotropy
Fluorescence Electric fields Electron transfer Transfer reactions Anisotropy
2016/5/20
The fluorescence intensity from randomly oriented, immobilized Rb. sphaeroides reaction centers at 77 K increases in the presence of an externally applied electric field. We have proposed that this in...
Electric Field Modulation of the Fluorescence Spectrum from Rhodobacter Sphaeroides Reaction Centers
fluorescence counterstain nuclear counterstain immunocytochemistry propidium iodide cell culture
2016/5/20
The fluorescence intensity from randomly oriented Rhodobacter ( Rb.) sphaeroides photosynthetic reaction centers at 77 K increases in an applied electric field. This is ascribed to a net reduction in ...
Power spectrum features of the near-Earth atmospheric electric field in Kamchatka
atmospheric quasi-static electric field atmospheric precipitation atmospheric waves
2015/9/14
Power spectrum of the diurnal variations of the quasi-electrostatic field Ez in the near-Earth atmosphere have been presented for the first time. The Ez power spectrum variations in the period of fine...