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Thiourea dioxide: An efficient and reusable organocatalyst for the rapid one-pot synthesis of pyrano[4, 3-b]pyran derivatives in water
Pyrano[4,3-b]pyran Thiourea dioxide 4-Hydroxy-6-methylpyran-2-one One-pot synthesis
2014/3/11
A series of pyrano[4,3-b]pyran derivatives have been synthesized in excellent yields by the reaction of aromatic aldehydes with malononitrile or cyanoacetate and 4-hydroxy-6-methylpyran-2-one in water...
In situ generation of trityl carbocation (Ph3C+) as a homogeneous organocatalyst for the efficient synthesis of 4, 4’-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol)s
Trityl chloride (Ph3CCl) Trityl carbocation (Ph3C+) 4,4'-(Arylmethylene)-bis(3- methyl-1-phenyl-1H-pyrazol-5-ol) 3-Methyl-1-phenyl-1H-pyrazol-5(4H)-one Solvent-free synthesis
2014/3/11
Trityl chloride (Ph3CCl) efficiently catalyzes the condensation of 3-methyl-1-phenyl-1H-pyrazol- 5(4H)-one and aromatic aldehydes under mild and solvent-free conditions, affording 4,4'- (arylmethylene...
Mild and Highly Efficient Method for Synthesis of 14-Aryl(alkyl)- 14H-dibenzo[a,j]xanthenes and 1,8-Dioxooctahydroxanthene Derivatives Using Pentafluorophenyl Ammonium Triflate as a Novel Organocatalyst（图）
pentafluorophenyl ammonium triflate organocatalyst xanthene β-naphthol
2013/10/7
A simple and facile synthesis of 14-aryl and alkyl-14H-dibenzo[a,j]xanthenes and 1,8-dioxooctahydroxanthene derivatives has been successfully developed by treatment of β-naphthol or dimedone with alde...
Protection of Hydroxyl Groups as a Trimethylsilyl Ether by 1,1,1,3,3,3-Hexamethyldisilazane Promoted by Aspartic Acid as an Efficient Organocatalyst（图）
alcohol phenol 1,1,1,3,3,3-hexamethyldisilazane trimethylsilylation protection
2013/10/14
A wide variety of alcohols and phenols were protected as trimethylsilyl ethers using 1,1,1,3,3,3-hexamethyl disilazane catalyzed by aspartic acid as a non-toxic, metal-free, and green organocatalyst a...