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In an effort to develop new organotin materials for investigation and biocidal evaluation, a series of compounds with the general formula R4 - nSnLn (where R = CH3, n-C4H9, C6H5, C6H5CH2 and L = 3-(N-...
Mixture experimental design was used to enhance the separation selectivity of metal ions in nonaqueous capillary electrophoresis. The separation of cations (Ag, Fe, Cr, Mn, Cd, Co, Pb, Ni, Zn and Cu) ...
Experimental values of rate constants for the heterogeneous transfer of electrons to methyl viologen, diquat viologen, benzyl viologen and n-butyl viologen monocations were determined. The process was...
A molecular bowl with barium ion covering one portal of decamethylcucurbit[5]uril as a ‘metal-ion-bottom’ has been synthesized. The structure of the molecular bowl has been confirmed by the single cry...
Proton conducting properties of benzimidazole (BnIm) doped poly(vinylphosphonic acid) (PVPA) were studied. The doping ratio, x, which is the number of moles of BnIm per mole of polymer repeat unit, va...
Alumina powder is impregnated with cobalt in the concentration range 5% to 20% (w/v) and is characterized by nitrogen adsorption at 77 K by continuous flow method using the Quantasorb sorption system....
A new glass coating system, containing g- glycidoxypropyltrimethoxysilane/Cr3+ (system I:GLYMO/ Cr3+) and g-glycidoxypropyltrimethoxysilane/N-aminoethyl-3- aminopropyltrimethoxysilane/Cr3+ (system II:...
以(Bu4N)4[α-Mo8O26]和各种取代苯胺及其盐酸盐为原料, 在碳二环己基亚胺(DCC)存在下, 经脱水反应,合成了多种六钼酸根有机亚胺衍生物, 并用元素分析,1H-NMR,IR和UV-Vis光谱等进行表征,重点研究了六钼酸根有机亚胺衍生物在乙腈溶液中的紫外光谱。研究结果表明,该类化合物具有典型的分子内电子转移的紫外-可见光谱特征,其特征峰位移Δλmax与苯胺的苯环取代基的共轭效应指数(σ...
Potentiodynamic and potentiostatic polarizations, and a rotating disk electrode technique were used to study the influence of diffusion on the anodic reactions of tungsten (W) in a broad pH range (\si...
The determination of fluoride in some environmental samples was performed using a fluoride ion-selective electrode. Fluoride concentrations were determined in drinking waters (from different provinces...
采用X射线衍射技术分析了SrCO3和CeO2(摩尔比2∶1)混合粉料经不同温度与时间反应后的物相组成。发现Sr2CeO4物相存在着两种形成机制。当烧结温度高于1 000 ℃时,Sr2CeO4由中间相SrCeO3和SrCO3反应生成;而当温度较低时,Sr2CeO4直接由两种原始粉料反应生成。形成机制的差别对Sr2CeO4激发光谱产生明显的影响,由前者形成的Sr2CeO4, 强激发峰位于280 nm左...
通过溶胶-凝胶法制备CeOx/ZnO纳米复合粉体,并对其结构和光致发光特性进行了研究。发现500 ℃烧结出的复合粉体在502 nm处的绿光发射同纯ZnO的相比有显著的增强;600 ℃烧结的样品在603 nm出现新的发光峰。通过XRD和XPS分析认为荧光增强的主要原因同粉体中铈主要以Ce3+形式存在有关,新的发光峰可能来源于ZnO/CeO2界面处形成的新的能级跃迁。
Two different mononucleating ligands incorporating N4 and N2S2 donor units, 2-(1,3-benzothiazole-2-yl-methyl)-1,3-benzothiazole (L1) and N,N'-bis-(2-amino-phenyl)-malonamide (H2L2) were synthesized by...
用电感耦合等离子体(ICP)发射光谱法直接测定世界珍稀濒危鸟类——朱鹮羽毛中Cu,Zn,Mn,Ni,Cr,Fe,Mo七种元素的含量。结果表明,此方法简便,具有良好的精密度和准确性。

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