搜索结果: 1-15 共查到“化学工程 Fe3O4”相关记录20条 . 查询时间(0.046 秒)
Fe3O4 quantum dots embedded in porous carbon microspheres for long-life lithium-ion batteries
Ions Iron oxides Magnetite Micelles Microspheres
2023/6/21
We report here Fe 3 O 4 quantum dots embedded Fe 3 O 4 @C electrode materials via a facile micelle-colloid template method for pushing forward the Li-ion battery technology. To improve uniform dispers...
Polyvinyl amine coated Fe3O4@SiO2 magnetic microspheres for Knoevenagel condensation
Basic magnetic catalyst Fe3O4 nanoparticle Polyvinyl amine Knoevenagel condensation
2014/3/11
Polyvinyl amine coated Fe3O4@SiO2 composite microspheres with a core-shell structure were prepared and employed as a magnetic catalyst for Knoevenagel condensation under mild conditions. The catalyst ...
Fe3O4 Nanoparticles as an Efficient and Magnetically Recoverable Catalyst for the Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones under Solvent-Free Conditions(图)
dihydropyrimidinones dihydropyrimidinthiones ferroferric oxide nanoparticle one-pot condensation solvent-free
2013/10/12
The catalytic activity of Fe3O4 nanoparticles (NPs) in a one-pot three component condensation reaction consisting of an aromatic aldehyde, urea or thiourea, and a β-dicarbonyl under solvent-free condi...
Pt/Au/Fe3O4的制备及其电化学性能
Pt/Au/Fe3O4 阳极催化剂 甲醇还原剂 电化学性能
2014/4/2
以制得的纳米Fe3O4颗粒作为载体,用还原法将还原出的Au与Pt分别负载到Fe3O4颗粒表面,制得纳米Pt/Au/Fe3O4复合材料。对Pt/Au/Fe3O4进行紫外可见光吸收光谱、透射电子显微镜、X射线衍射及光电子能谱等物理表征,结果表明,Au与Pt均匀地沉积到了Fe3O4纳米颗粒表面。对纳米Pt/Au/Fe3O4复合材料进行循环伏安扫描,当H2PtCl6的加入量达到8 mL时,Pt/Au/Fe...
介绍了一种采用无毒廉价的前驱物制备Fe3O4@SiO2-Ag磁性纳米微球的快捷方法,制备的Fe3O4@SiO2-Ag纳米微球在NaBH4存在下可以催化还原染料污染物.实验结果表明,Fe3O4@SiO2-Ag磁性纳米粒子保持了Ag纳米粒子和Fe3O4纳米粒子的双重优点,不仅对染料罗丹明B和曙红Y具有良好的催化还原效率,而且可以在外加磁场作用下从溶液中快速有效的分离.催化还原反应速率与反应温度及Fe3...
Nano-Fe3O4 Encapsulated-Silica Particles Bearing Sulfonic Acid Groups as a Magnetically Separable Catalyst for Highly Efficient Knoevenagel Condensation and Michael Addition Reactions(图)
magnetic nanoparticle silica Knoevenagel condensation Michael addition cyclic diketone
2013/10/4
Sulfonic acid-functionalized silica-coated nano-Fe3O4 particles (Fe3O4@SiO2-SO3H) have been prepared as a novel heterogeneous acid using a facile process. The material was subsequently identified as a...
采用聚苯乙烯(PS)包裹 Fe3O4 磁性纳米粒子,制得 Fe3O4@PS 复合微球,以此作为磁性载体, 通过微球表面的羧基将聚酰胺-胺类树形大分子(PAMAM)连接到磁性载体上, 然后使 Ag 纳米粒子镶嵌在树形分子层中,制得可再生的金属复合催化粒子Fe3O4@PS@PAMAM-Ag.并采用红外光谱、扫描电镜、电感耦合等离子体质谱 (ICP-MS) 和 X 射线光电子能谱等方法对复合催化粒子进行...
Novel Approach to Benzimidazoles Using Fe3O4 Nanoparticles as a Magnetically Recoverable Catalyst(图)
ferroferric oxide nanoparticle 1,2-phenylenediamine orthoester benzimidazole
2013/10/9
Magnetically recoverable Fe3O4 nanoparticles have been synthesized as a catalyst for the cyclocondensation of 1,2- phenylenediamines with orthoesters under solvent-free conditions. Catalyst loadings c...
Direct Hydroxylation of Benzene to Phenol over Fe3O4 Supported on Nanoporous Carbon(图)
nanoporous carbon ferroferric oxide hydroxylation of benzene phenol
2013/10/15
Fe3O4/CMK-3 was prepared by impregnation and used as a catalyst for the direct hydroxylation of benzene to phenol with hydrogen peroxide. The iron species in the prepared catalyst was Fe3O4 because of...
溶剂热合成纳米Fe3O4及其性能表征
球形Fe3O4 溶剂热合成 磁性能 纳米粒子
2010/9/25
采用溶剂热还原方法,以FeCl3·6H2O和乙二醇为原料,采用双表面活性剂,在180 ℃条件下合成了粒径从72 nm到447 nm的纳米Fe3O4粒子,研究了NaAc·3H2O在体系中的作用,探讨了反应时间,铁源浓度和表面活性剂等反应条件对产物的影响.利用X射线粉末衍射(XRD),傅里叶变换红外光谱仪(FT-IR)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)和振动样品磁强计(VSM)对产物...
以甲基丙烯酸-2-羟基乙酯为单体,N,N¢-亚甲基双丙烯酰胺为交联剂,采用光化学方法在Fe3O4磁性液体中制备了磁性聚甲基丙烯酸-2-羟基乙酯微球,合成了含有稀土元素Tb的荧光磁性高分子微球,以牛血清白蛋白为模型对微球固定释放蛋白能力进行了研究,用VSM, PCS, FT-IR, TG-DTA, SEM, FS, UV-Vis等技术对微球的性能进行了表征. 结果表明,荧光磁性高分子微球粒径为29....
P(St-GMA-DVB)/Fe3O4高分子磁性微球的合成与表征
化学共沉淀 悬浮聚合 高分子磁性微球
2009/11/13
以FeCl3×6H2O和FeCl2×4H2O为原料,采用化学共沉淀法制备了Fe3O4油基磁流体,设计的合成工艺克服了合成磁流体过程中Fe3O4磁性粒子易团聚的缺点,合成了具有很好分散性和稳定性的磁流体,比饱和磁化强度达72.60 emu/g. 采用悬浮聚合方法合成了聚苯乙烯-甲基丙烯酸缩水甘油酯-二乙烯基苯[P(St-GMA-DVB)]高分子磁性微球,搅拌转速对磁性微球粒径影响大,磁性微球粒径在5...
软模板法制备Fe3O4空心结构微球
Fe3O4微球 软模板 制备
2009/11/5
以FeCl3×6H2O和NH4Ac为反应物,乙二醇为溶剂热介质,制备了Fe3O4空心结构微球. 通过X射线衍射、场发射扫描电子显微镜、透射电子显微镜和振动样品磁强计对产物的结构、形貌及磁性能进行了表征,并研究了反应温度和反应时间对产物形貌的影响,得出了制备Fe3O4空心结构微球适宜的反应温度为200℃,反应时间为12 h. 此条件下得到的产物形貌均匀且表面光滑,平均粒径约为400 nm,具有铁磁性...
超声合成Fe3O4@SiO2复合纳米磁性粒子用于质粒DNA的提纯
复合纳米磁性粒子 超声 Fe3O4@ SiO2 DNA 提取
2009/10/15
用超声合成了Fe3O4@SiO2复合纳米磁性粒子, 并用于质粒DNA的提取. 用透射电镜(TEM)、红外光谱(FT-IR)、震动样品磁场计(VSM)、X光电子能谱仪(XPS)等方法对合成的复合磁性粒子的表面形貌、结构、磁性质等进行了表征, 合成的复合磁微粒粒径分布均匀, 在15~20 nm, 磁响应性好. 用该复合磁微粒提取DNA的纯度能达到A260/A280= 1.8±0.1, 琼脂糖电泳证明质...