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Origins of the Sensitivity of Molecular Vibrations to Electric Fields:Carbonyl and Nitrosyl Stretches in Model Compounds and Proteins
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2016/5/24
The vibrational Stark effect (VSE) is the effect of an electric field on the vibrational spectrum. Typically, the largest change induced by an electric field is the linear frequency shift whose sensit...
Vibrational Stark Effects of Nitriles II. Physical Origins of Stark Effects from Experiment and Perturbation Models
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2016/5/23
Vibrational Stark effects, which are the effects of electric fields on vibrational spectra, were measured previously for the C−N stretch mode of several small nitriles, yielding difference dipol...